PRODUCTION AND APPLICATIONS OF GRAPHENE AND ITS COMPOSITES

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PRODUCTION AND APPLICATIONS OF GRAPHENE AND ITS COMPOSITES ( production-and-applications-graphene-and-its-composites )

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2.3.2.1.3. LPE in low boiling solvents ................................................................40 2.3.2.1.4. Sonication induced defects ...............................................................41 2.3.2.2. Surfactant-based LPE ..............................................................................42 2.3.2.2.1. 2.3.2.2.2. 2.3.2.2.3. LPE in aqueous media .......................................................................42 LPE in organic solvents ......................................................................45 Polymer-assisted LPE.........................................................................45 2.3.2.3. 2.3.2.4. 2.3.2.5. 2.3.2.6. Co-solvent-based LPE..............................................................................46 Solvent exchange methods.....................................................................48 Graphite intercalation compound-based LPE.........................................49 Ionic liquid-based LPE .............................................................................50 2.3.2.6.1. Sonication-assisted IL-based LPE.......................................................50 2.3.2.6.2. Grinding-assisted IL-based LPE..........................................................50 2.3.3. Electrochemical exfoliation of graphene .......................................................51 2.3.3.1. Anodic exfoliation ...................................................................................52 2.3.3.2. Cathodic exfoliation ................................................................................53 2.3.4. Other top-down methods ..............................................................................53 2.3.4.1. High-shear exfoliation.............................................................................53 2.3.4.2. Sonication free LPE .................................................................................54 2.3.5. Epitaxial graphene..........................................................................................55 2.3.5.1. CVD-grown graphene..............................................................................55 2.3.5.1.1. Large single crystal graphene on Cu..................................................56 2.3.5.1.2. Transfer of CVD graphene on substrates ..........................................58 2.3.5.2. Thermal decomposition of silicon carbide .............................................60 2.4. Production, Structure and Properties of Graphene Oxide ..................................60 2.4.1. Production of Graphene oxide.......................................................................60 2.4.2. Structure of Graphene oxide .........................................................................61 3

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