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GUIDE Lithium Ion and Sodium Ion Batteries 147 Hazards


Lithium Hazard Technology Report
This comprehensive report provides a technical analysis of large-scale lithium energy storage systems, focusing on 1 MW+ containerized solutions. It delves into the risks of thermal runaway, fire hazards, and toxic gas emissions, along with strategies for fire prevention, monitoring, and site-specific installation considerations. Additionally, it covers the impact of lithium fires on insurance costs and outlines best practices for safety, scalability, and operational efficiency. Emerging technologies and regulatory frameworks are also discussed to provide actionable insights for manufacturers, operators, and policymakers.



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Lithium Ion and Sodium Ion Batteries GUIDE 147
EMERGENCY RESPONSE
FIRE
• A lithium ion or sodium ion battery fire may reignite at any point after the initial fire is extinguished, up to weeks later.
• Use thermal imaging, if available, to continuously monitor the battery.
• Reignition can be accompanied by off-gassing of white smoke or electrical arcs or sparks that reignite
with visible flames or fire.
CAUTION: The use of salt water for firefighting is not recommended since it may increase production of
hydrogen and hydrogen fluoride gas.
Vehicle Fire
• If battery is not connected to a vehicle, see “Small Fire or Fire Involving Small Battery” below.
• Check manufacturer’s specific emergency response guide before attempting to disable vehicle.
• Turn off the ignition and disconnect the 12-volt battery if it can be done safely.
• Never cut the high voltage (HV) or medium voltage (MV) cabling.
• Never touch damaged or submerged HV or MV cables or components.
• If available, use large amount of water to extinguish or suppress a high-voltage battery fire. Using small
amount of water could release toxic gases.
• If possible, spray water directly onto battery.
• DO NOT pierce, cut, pry, or dismantle any of the vehicle's structure to access the battery. Contact with a
high voltage component may cause an electric shock.
Small Fire or Fire Involving Small Battery (e.g., personal electronic devices, e-bike, etc.)
• Water spray only (large amounts); do not use dry chemical, CO2 or Halon®.
Large Fire or Fire Involving Large Battery or Multiple Small Batteries
• Allow battery fire to burn itself out and protect surroundings.
• Safely remove undamaged containers from area.
• Apply water spray to neighboring batteries to reduce the spread of the hazard.
SPILL OR LEAK
• ELIMINATE all ignition sources (no smoking, flares, sparks or flames) from immediate area.
• Do not touch or walk through spilled material.
• Absorb with earth, sand or other non-combustible material.
• Leaking batteries and contaminated absorbent material should be placed in metal containers.
FIRST AID
Refer to the “General First Aid” section.
ERG 2024 Page 225

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