PDF Publication Title:
Text from PDF Page: 230
2.2.5. A Possible Reaction Network for Catalytic Hydrodeoxygenation and Methylation of m-Cresol Catalysts 2016, 6 10 Based on the discussion above, a possible reaction network for catalytic hydrodeoxygenation and methylation of m-cresol over Pt/HZSM-5 is shown in 2.2.5. A Possible Reaction Network for Catalytic Hydrodeoxygenation and Methylation of m-Cresol Figure 6. First of all, m-cresol could be converted into toluene via HDO reaction. BTahsednotnoltuhendeiscuosusilodnbaebofvuer,thaeproscsoibnlveerretaecdtiointnoetawlokraknfeosr acnatdalyxtyiclehnyedsro(dpe-o/xmyg-xenyalteinone and methaynldatio-nxyoflemn-ec)retshorlouvgerhPmt/HeZthSyMla-5tioisns.hOowfncoinuFrisgeu,rteh6e. fFuirstthoeframll,emth-cyrelasotilocnouoldf xbyelceonevserted intogteonlueernaetevsiapoHlyDaOlkryelactteiodnb.eTnhzeennteosl.ueTnweocouthlderbepafruartlhlelracloknyvlearttieodnirnetoacatilkoannepsatahnwdaxyslenes (p-/mof-xymle-ncreeasnodlow-xyitlhenem) tehtrhoaungholmeatrheyladteiosnc.rOibfecdoubrsel,othwe:furOth-earlmkyetlhaytiloatnionooff mxy-lcernesoglenteorates polymalkeythlayteladnbiesnozlen,eas.nTdwoC-oathlkeryplatriaollnelianlktoylaxtiyolnenreoalcstiownhpiacthwcaoyuslodfmb-ecreaslosolwfiothrmetdhabnoylare descdribsepdrobpelorwti:oOn-aatlikoynlaotifomn-ocfrmes-ocrl.esTohletoHmDetOhyolafnxiysolelen,oalnsdgCe-naelkrayltaetsioxnyilnetnoexsyalecncolmswpahnicihedcould be awlsoitfhortmhedfboyrdmisaptriopnorotifonpaotiloynaolkf myl-actresdolp. ThheenHolDsOasofbxy-lepnroldsugecntse.ratePshxeynleonlescoaucclodmbpeanied withdtehoexfyogrmenataitoendotfopboelynazleknyleawtedhipchencolusldasbbeyc-pornovdeurctes.dPihnetnootlocluouelndebtehdroeouxgyhgmeneatehdyltaotbioenz. ene whicmh-Ccoruelsdoblecocuonldvebrtedisionmtoetroilzuednetothoro-curgehsomlevthiaylatnioins.om-eCriezsaotlioconurldeabcetiiosonmwerhizicehd ctouo-lcdresol via abneiscomnevreizratetidonirnetaoctmionetwhhyiacnhicsoulledabnedcoxnyvelertneodlisntboymmetheythanyilsaotlieoann,daxsylweneollsabsytmoleutheynlaetion, as wveilal aHsDtoOlu.ene via HDO. H2O CH3OH 14 4 CH3 CH3 CH3OH 11 H2O OH CH3 (CH3)2 H2O CH3OH OCH3 H2O 10 CH3OH OH OH CH3 Alkanes 3 H2 2 OH H2O 1 H2 5 H2O + OH 7 H2 H2O 12 CH3 H2 6 H2 CH3 H2O H2O CH3 CH3OH 13 CH3OH H2O CH3 CH3 Figure 6. A possible reaction routes for catalytic hydrodeoxygenation and Figure 6. A possible reaction routes for catalytic hydrodeoxygenation and methylation of methylation of m-cresol over Pt/HZSM-5. The blue line represents the reaction m-cresol over Pt/HZSM-5. The blue line represents the reaction involved in methanol. involved in methanol. 2.3. Catalyst Screening In this section, catalytic hydrodeoxygenation and methylation of m-cresol (C/M ratio of 1/4) over In this section, catalytic hydrodeoxygenation and methylation of m-cresol (C/M 2.3. Catalyst Screening different catalysts were studied to investigate the effect of the nature of the supporter and metal on the ratio of 1/4) over different catalysts were studied to investigate the effect of the product distribution. Table 3 shows the conversion of m-cresol and product distribution at 698 K over seven kinds of catalysts. At 698 K, the abundant compounds are toluene and p-/m-xylene on the catalysts except 1.0 wt. % Pt/B-25. For the Pt/HZSM-5 2c1a5talysts with parent supporter loading same metal content, the toluene and p-/m-xylene selectivities are, respectively, in the range of 32.4% to 36.9% and 27.8% to 28.7%, and the conversion of m-cresol and product distribution does not exhibit a distinct relation to the SiO2/Al2O3 ratio (acid amount). Nevertheless, for Pt/Z-57 with lower Pt content, the CH3OH 8 9H2O (CH3)2 CH3PDF Image | Zeolite Catalysis
PDF Search Title:
Zeolite CatalysisOriginal File Name Searched:
Zeolite_Catalysis.pdfDIY PDF Search: Google It | Yahoo | Bing
NFT (Non Fungible Token): Buy our tech, design, development or system NFT and become part of our tech NFT network... More Info
IT XR Project Redstone NFT Available for Sale: NFT for high tech turbine design with one part 3D printed counter-rotating energy turbine. Be part of the future with this NFT. Can be bought and sold but only one design NFT exists. Royalties go to the developer (Infinity) to keep enhancing design and applications... More Info
Infinity Turbine IT XR Project Redstone Design: NFT for sale... NFT for high tech turbine design with one part 3D printed counter-rotating energy turbine. Includes all rights to this turbine design, including license for Fluid Handling Block I and II for the turbine assembly and housing. The NFT includes the blueprints (cad/cam), revenue streams, and all future development of the IT XR Project Redstone... More Info
Infinity Turbine ROT Radial Outflow Turbine 24 Design and Worldwide Rights: NFT for sale... NFT for the ROT 24 energy turbine. Be part of the future with this NFT. This design can be bought and sold but only one design NFT exists. You may manufacture the unit, or get the revenues from its sale from Infinity Turbine. Royalties go to the developer (Infinity) to keep enhancing design and applications... More Info
Infinity Supercritical CO2 10 Liter Extractor Design and Worldwide Rights: The Infinity Supercritical 10L CO2 extractor is for botanical oil extraction, which is rich in terpenes and can produce shelf ready full spectrum oil. With over 5 years of development, this industry leader mature extractor machine has been sold since 2015 and is part of many profitable businesses. The process can also be used for electrowinning, e-waste recycling, and lithium battery recycling, gold mining electronic wastes, precious metals. CO2 can also be used in a reverse fuel cell with nafion to make a gas-to-liquids fuel, such as methanol, ethanol and butanol or ethylene. Supercritical CO2 has also been used for treating nafion to make it more effective catalyst. This NFT is for the purchase of worldwide rights which includes the design. More Info
NFT (Non Fungible Token): Buy our tech, design, development or system NFT and become part of our tech NFT network... More Info
Infinity Turbine Products: Special for this month, any plans are $10,000 for complete Cad/Cam blueprints. License is for one build. Try before you buy a production license. May pay by Bitcoin or other Crypto. Products Page... More Info
| CONTACT TEL: 608-238-6001 Email: greg@infinityturbine.com | RSS | AMP |