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Analysis of Fluid Flow in Redox Flow Batteries

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Analysis of Fluid Flow in Redox Flow Batteries ( analysis-fluid-flow-redox-flow-batteries )

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flow, concentration, and current distribution due to their large sizes, which causes lower energy efficiency. [5] 1.2- All-vanadium redox flow batteries Redox flow battery (RFB) consists of two electrolyte reservoirs, placed at the two sides of an electrochemical reactor, as shown in Figure 1. 3. Electrolytes are pumped continuously in and out of the reactor, forming reaction cycles. A fraction of reactants convert to products in each reaction cycle. For a cycle, the extent of each reaction depends on the residence time of the electrolytes in the reactor and the kinetics of the reactions. A specified ion is responsible for the exchange of electrons with the external electrical circuit on both sides of the electrochemical reactor; the ion- exchange membrane (IEM) allows that ion to pass and blocks other ions. Electrolytes are liquid solutions in flow batteries. Reactants and products are dissolved in electrolytes for RFBs, as opposed to hybrid flow batteries (HFBs), where multi-phase reactions occur and the presence of a solid-phase reactant is necessary for HFB operation. [2,6–8] 4

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