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Analysis of Fluid Flow in Redox Flow Batteries

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Analysis of Fluid Flow in Redox Flow Batteries ( analysis-fluid-flow-redox-flow-batteries )

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To model the flow in FFs, it is assumed that the flow rate is analogous to the electrical current and the pressure is analogous to the electrical potential due to their same behavior in series or parallel channels or electrical circuits. In electrical circuits, the relationship between electrical current and potential is expressed as: 𝑉 = 𝑅𝑒𝑙𝐼 where V, I, and Re are electrical potential, current, and resistance, respectively. The same relationship may be written for Q and Ξ”P as well: π›₯𝑃 = 𝑅 𝑄 (3.32) π‘šπ‘£ where Rv is the viscous resistance for the respective porous or non-porous medium. The viscous resistances for the channels and porous medium can be obtained by manipulating Equations 3.29 and 3.31: 𝑄=πœ‹π·h4βˆ†π‘ƒ →𝑅 =4πΆπœ‡π‘™ (3.33) 4πΆπœ‡π‘™ π‘š 𝑐 πœ‹π·h4 βˆ†π‘ƒπ‘š=πœ‡ 𝑄 →𝑅𝑝=πœ‡π‘€π‘Ÿ (3.34) π‘€π‘Ÿ π‘˜ hπ‘π‘™π‘Ÿ π‘˜hπ‘π‘™π‘Ÿ Kirchhoff’s laws quantify how current flows through and how potential varies in an electrical circuit. They are described as the following statements: 1- In each node, the sum of the current is zero (Ξ£I=0). 2- In each loop, the sum of the potential is zero (Ξ£V=0). 2a- The potential difference between two nodes is equal to the resistance between them multiplied by the passing current. (Vij= RijIij) 37

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