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Figure 5. The Design and Characterization of Different Metal- and Organic-Based DESs (A) Standard redox potentials of Zn, Al, and Fe and active concentrations of corresponding DESs. Adapted with permission from Zhang et al.43 Copyright 2018 American Chemical Society. (B) Schematic of preparation of Fe DESs using FeCl3,6H2O and urea and the proof-of-concept Li-Fe battery based on Fe-DES. Reprinted with permission from Wang et al.49 Copyright 2016 Royal Society of Chemistry. (C) 27Al NMR analysis of Al DES/DCE at different charging states. Reprinted with permission from Zhang et al.45 Copyright 2017 Wiley-VCH Verlag GmbH & Co. KGaA. (D) Raman spectra of different Fe DESs. Reprinted from Zhang et al.50 Copyright 2017 Elsevier. (E) Phase diagram of the MTLT mixture with the MT ratio. Reprinted with permission from Takechi et al.52 Copyright 2015 Wiley-VCH Verlag GmbH & Co. KGaA. (F) Molecular electrostatic potential of LiTFSI-NMePh-urea eutectic electrolyte with molar ratio of LiTFSI:NMePh:urea = 2:1:3. Reprinted from Zhang et al.53 Copyright 2018 Elsevier. (G) The relationship of solubility of H2BQ and concentrations of urea. Reprinted with permission from Ding et al.54 Copyright 2018 American Chemical Society. Chem 5, 1964–1987, August 8, 2019 1973PDF Image | Development of Redox Flow Batteries Based on New Chemistries
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