Effect of Fe3 positive electrolyte vanadium redox flow

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Effect of Fe3 positive electrolyte vanadium redox flow ( effect-fe3-positive-electrolyte-vanadium-redox-flow )

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0.08 2 1 6 1 0 mol l–1 5 0.00893 mol l–1 3 0.0161 mol l–1 0.06 4 5 0.0232 mol l–1 0.04 0.02 0 –0.02 –0.04 –0.06 5 0.0196 mol l–1 6 0.0286 mol l–1 3 0 0.2 1.0 1.2 4 2 0.006 0.004 0.002 0 –0.002 –0.004 0.4 0.6 0.8 potential/V versus SCE Figure 2. CV curves of 1.6 M VOSO4 at the scan rate of 10 mV s21 with different concentrations of Fe(III). 0.4 0.6 1.4 1.6 1.8 potential/V versus SCE Table 2. Main data from CV curves of 1.6 M VOSO4 with different concentrations of Fe(III). 0.00893 mol l–1 0.0161 mol l–1 0.0196 mol l–1 4 0.0232 mol l–1 0.0286 mol l–1 0.04 1 2 0.03 3 4 0.02 5 0.01 0 –0.01 –0.02 –0.03 –0.04 0 Figure 3. CV curves of 2.8 M H2SO4 solution with different concentrations of Fe(III) at a scan rate of 0.1 V s21. 0.2 0.4 potential/V versus SCE 1 2 5 3 0.6 0.8 1.0 solution (mol l21) anodic peak cathodic peak jpa (mA cm22) Epa (V) jpc (mA cm22) Epc (V) DEp (V) Jpa/jpc 0 71.73 0.00893 53.99 0.0161 58.56 0.0196 63.66 0.0232 54.60 0.0286 64.99 1.108 51.54 1.045 37.21 1.083 40.64 1.199 46.14 1.240 37.43 1.075 45.92 0.751 0.357 0.789 0.256 0.758 0.325 0.689 0.510 0.646 0.594 0.772 0.303 1.39 1.45 1.44 1.38 1.46 1.42 royalsocietypublishing.org/journal/rsos R. Soc. open sci. 6: 181309 Downloaded from https://royalsocietypublishing.org/ on 11 January 2023 current density (A cm–2) current density (A cm–2) current density (A cm–2)

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