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Contents Acknowledgements ...................................................................................................................i Abstract .................................................................................................................................... iii 1. Introduction........................................................................................................................1 Energy Storage and Renewables .................................................................................1 Current State of Storage Technology..........................................................................1 Mechanical Energy Storage Technologies ..................................................................1 Pumped Hydro Electricity Storage ......................................................................2 Compressed Air Energy Storage..........................................................................2 Chemical Energy Storage Technologies .....................................................................3 Lithium-ion Batteries ...........................................................................................3 Lead Acid Batteries..............................................................................................3 Redox Flow Batteries...........................................................................................3 Electrolysis and Fuel Cells for Hydrogen ............................................................5 Energy and Power .......................................................................................................6 Levelised Cost of Electricity.......................................................................................8 Thesis scope ..............................................................................................................10 2. Vanadium Redox Flow Batteries Review........................................................................12 Current Performance of VRFB .................................................................................13 Electrochemical Processes within a VRFB...............................................................14 Performance Limiting Aspects of VRFB ..................................................................15 Electron Transfer Kinetics ........................................................................................17 Mass Transfer............................................................................................................18 Electrolyte Considerations .................................................................................19 viiPDF Image | Electron Transfer Kinetics in Redox Flow Batteries
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