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5 Single fibre electrode measurements - a versatile strategy for assessing the non-uniform kinetics The uncertainties were estimated by finding the k0 values at which the simulated peak separation differed from the experimental peak separation by more than 2 mV, providing upper and lower limits for the rate constant (Table 5.1). Table 5.1: Fitted rate constants from simulated voltammograms recorded at 200 mV s-1 at single carbon fibre electrodes in 10 mM ferricyanide and 10 mM ferrocyanide. Fibre # 1 2 3 4 5 6 7 8 9 10 11 12 Average k0 (cm s-1) 0.0098 ± 0.0003 0.0160 ± 0.0006 0.0087 ± 0.0002 0.0100 ± 0.0003 0.0097 ± 0.0002 0.00160 ± 0.00003 0.0064 ± 0.0002 0.0123 ± 0.0001 0.0100 ± 0.0003 0.0027 ± 0.0002 0.00096 ± 0.00003 0.00140 ± 0.00002 0.0075 ± 0.0030 57PDF Image | Electron Transfer Kinetics in Redox Flow Batteries
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