PDF Publication Title:
Text from PDF Page: 077
5 Single fibre electrode measurements - a versatile strategy for assessing the non-uniform kinetics To illustrate the combined influence of the void size and rate constant distributions, an experimental cyclic voltammogram was compared to simulations based on four different combinations of parameters. These were the average void diameter size (40.8 μm) and average rate constant (0.0075 cm s-1) (Figure 5.5a); the measured void size distribution and the average rate constant (Figure 5.5b); the average void size and the rate constant distribution (Figure 5.5c); and the measured void size and rate constant distribution (Figure 5.5d). Figure 5.5: Comparison of experimental and simulated cyclic voltammograms, calculated using different combinations of parameters. The experimental cyclic voltammograms were obtained at a carbon felt electrode in a solution of 0.1 mM ferricyanide and 0.1 mM ferrocyanide, at a sweep rate of 100 mVs-1, compensated for ohmic resistance as outlined in Experimental section. a) Modelled using the average void diameter and average rate constant (40.8 μm and 0.0075 cm s-1). b) Modelled using the calculated void distribution (Figure 5.3b) and the average rate constant. c) Modelled using the average void diameter and the measured rate constant distribution. d) Modelled using the calculated void distribution and the measured rate constant distribution. 65PDF Image | Electron Transfer Kinetics in Redox Flow Batteries
PDF Search Title:
Electron Transfer Kinetics in Redox Flow BatteriesOriginal File Name Searched:
electron-transfer-flow-batteries-thesis.pdfDIY PDF Search: Google It | Yahoo | Bing
Salgenx Redox Flow Battery Technology: Salt water flow battery technology with low cost and great energy density that can be used for power storage and thermal storage. Let us de-risk your production using our license. Our aqueous flow battery is less cost than Tesla Megapack and available faster. Redox flow battery. No membrane needed like with Vanadium, or Bromine. Salgenx flow battery
CONTACT TEL: 608-238-6001 Email: greg@salgenx.com (Standard Web Page)