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Electron Transfer Kinetics in Redox Flow Batteries

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Electron Transfer Kinetics in Redox Flow Batteries ( electron-transfer-kinetics-redox-flow-batteries )

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7 Thermal Activation of Carbon Felt for the Positive Vanadium Redox Couple Interestingly the capacitance of GFE felt declined between 600 oC and 700 oC. The cause of this is unknown, but it does coincide with a noticeable decrease in mass of the felt. The change in capacitance at each thermal treatment is quantified relative to the as-received felts, (Table 7.1). Table 7.1:Change in capacitance relative to control felt for thermal treatment of each felt from cyclic voltammetry recorded in 0.5 M H2SO4 from cyclic voltammetry recorded at 100 mVs-1. Treatment Capacitance Increase (oC) G100 GFE C100 200 1.1 1.1 2.2 300 1.1 1.1 9.6 400 1.9 1.2 135.3 500 2.5 2.5 - 600 3.9 7.5 - 700 - 1.9 - 96

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Electron Transfer Kinetics in Redox Flow Batteries

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