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Electron Transfer Kinetics in Redox Flow Batteries

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Electron Transfer Kinetics in Redox Flow Batteries ( electron-transfer-kinetics-redox-flow-batteries )

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8 Half – cell performance of Carbon Felt Samples Charge / Discharge Measurements Charge / discharge measurements were carried out determine if the rate constants calculated from cyclic voltammetry and polarization curves accurately reflect the performance of the carbon felt when used in a working cell. As previously mentioned the voltage drop from electrical resistance was corrected for post run. In a full-cell, the electrical resistance is not typically corrected for, as the change in resistance can be due to the conductivity of the felt. However, in this half-cell set up changes in resistance are more likely due to changes in solution resistance from the distance of the reference electrode to the working electrode. The voltage efficiency (VE), coulombic efficiency (CE) and energy efficiency (EE) were calculated using Eqs. 2.5-2.7 and are presented, (Table 8.2). Table 8.2: Performance characteristics for selected carbon felt samples. Felt VE CE EE (%) (%) (%) GFE 81.9 93.8 76.8 G100 82.8 97.9 81.1 C100 87.1 98.2 85.5 GFE Thermal 89.1 98.5 87.7 k0app (cm s-1) 1.4 x 10-5 2.3 x 10-5 2.2 x 10-5 4.3 x 10-5 As expected based on the rate constant calculated from polarization curve measurements, the GFE Control felt sample had the lowest efficiency of the three felts (GFE, C100, G100). Whilst the GFE felt sample thermally treated at 600 oC showed a noticeable improvement in performance over the untreated felt, increasing energy efficiency from 76.8% to 87.7%. 120

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