Model-based Design Vanadium Redox Flow Batteries

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Model-based Design Vanadium Redox Flow Batteries ( model-based-design-vanadium-redox-flow-batteries )

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5.3 FEA simulations ........................................................................................................ 81 Chapter 6 Evaluation of the cell designs in a single-stack system............................ 85 6.1 Current state of science.............................................................................................. 85 6.2 System design ............................................................................................................ 85 6.3 Evaluation methodology ............................................................................................ 86 6.4 Comparison of two sample designs ........................................................................... 89 6.5 Evaluation of all twenty-four cell designs ................................................................. 95 6.6 Conclusion ............................................................................................................... 103 Chapter 7 Evaluation of the cell designs in a three-stack system ........................... 105 7.1 System design of the three-stack string system ....................................................... 105 7.2 Comparison of two sample designs for the three-stack string system..................... 106 7.3 Evaluation of the twenty-four cell designs in a three-stack string .......................... 111 7.4 Conclusion ............................................................................................................... 116 7.5 Implications for grid connection.............................................................................. 116 Chapter 8 Flow rate optimization............................................................................ 119 8.1 Current state of science............................................................................................ 119 8.2 Minimally required flow rate – Faraday’s law ........................................................ 120 8.3 Flow rate optimization basics .................................................................................. 121 8.4 Constant flow rate.................................................................................................... 122 8.5 V ariable flow rate – Conventional approach ........................................................... 125 8.6 V ariable flow rate - Innovative optimization approach ........................................... 127 8.7 Voltage-dependent FRCS – the stack voltage controller......................................... 130 8.8 Comparison of the FRCSs ....................................................................................... 133 8.9 Summary .................................................................................................................. 139 Chapter 9 Summary and Outlook............................................................................ 143 9.1 Summary.................................................................................................................. 143 9.2 Outlook .................................................................................................................... 144 Appendix A Appendix B Appendix C Appendix D Appendix E Summary of the essential equations used in the model ...................... 147 Additional data and calculations ......................................................... 151 Nomenclature ...................................................................................... 153 Bibliography ........................................................................................ 157 Author’s publication and supervised student theses ........................... 165 VI

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