Model-based Design Vanadium Redox Flow Batteries

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Model-based Design Vanadium Redox Flow Batteries ( model-based-design-vanadium-redox-flow-batteries )

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Section 2.4  Vanadium crossover J2Cross+ 􏱫J3Cross+􏱬 􏰵 J4Cross+ J5Cross+ (2-27) In short-term, the vanadium crossover influences the battery operation only in terms of efficiency. The vanadium crossover and the self-discharge reactions which it triggers in the opposite half-cell result in an equivalent self-discharging current, as shown in Figure 2-4. Figure 2-4: Equivalent currents due to the vanadium crossover through the membrane of a single 2000-cm2 cell and respective self-discharge reactions in the opposite half-cell 0 AMem 􏱫 0 􏱬 􏱭Mem 3􏰻c2C􏱆 􏱡 c2C􏱇􏱋D􏰽Mem 􏰷 2􏰻c3C􏱆 􏱡 c3C􏱇􏱋D3Mem 􏰷 􏰻c4C􏱆 􏱡 c4C􏱇􏱋D4Mem 􏱡2􏰻c2C􏱆 􏱡 c2C􏱇􏱋D2Mem 􏱡 􏰻c3C􏱆 􏱡 c3C􏱇􏱋D3Mem 􏰷 􏰻c5C􏱆 􏱡 c5C􏱇􏱋D5Mem 2.4.5 Numerical example 25

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