Model-based Design Vanadium Redox Flow Batteries

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Model-based Design Vanadium Redox Flow Batteries ( model-based-design-vanadium-redox-flow-batteries )

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Section 9.2  Outlook 88 a) System efficiency Base case 50% cell resistance 50% diffusion 50% cell resistance & 50% diffusion 86 84 82 80 78 76 74 72 23 b) Specific discharge capacity 22 21 20 19 18 17 16 15 0 20 40 60 80 100 0 20 40 60 80 100 Current density in mAcm-2 Current density in mAcm-2 Figure 9-1: Reduced cell resistance and diffusion coefficients increase the round-trip efficiency and the discharge capacity of future VRFBs. 9.2.2 Outlook on model-based works In the large number of published model-based studies, the model validation is not a very popular topic, in particular regarding commercial-scale systems. Hence, the collaboration of manufacturers and research institutes should be intensified, in order to make sure that the presented virtual models also unfold an actual practical benefit. Regarding the model extensions, the plug flow reactor principle can overcome the simplification of a perfectly mixed cell [19, 100]. Further, first works try to capture the topic of ageing [27]. For long-term operation, the effect of bulk electrolyte and water transfer across the membrane should be included in lumped-parameter models, e.g. as shown in [24]. The standard electrolyte is an oversaturated solution. Thus, a certain temperature window has to be kept in order to prevent the precipitation of the vanadium salts. Consequentially, sophisticated thermal models of the VRFB are of high interest and should be included in future studies. 145

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