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Quinones/Hydroquinones: Reversible or Irreversible hydro- quinone QH2 +e- QH2+ -e- +e- QH22+ O– proton and electron addition reactions with known and estimated pKa’s O “pBQ” OH OH+ Q2- -e- -e- +e- Q- +e- Q para- benzo- quinone O– O OH 11.84 +H+ 4.1 +H+ ~ -7 +H+ OH + QH- -e- +e- QH -e- +e- QH+ O– 9.85 +H+ OH -e- ~ -1 +H+ < -7 +H+ O OH+ Quan, Sanchez, Wasylkiw, Smith, “Voltammetry of Quinones in Unbuffered Aqueous Solution...”, JACS 129, 12847 (2007)PDF Image | Organic-Based Aqueous Flow Batteries for Massive Energy
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