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i–1 (mA–1) Redox couple k0 [cm/s] (electrode) / mV 13 AQDS/ AQDSH2 7.2 x 10-3 (carbon) 28 Br2/Br- 0 0.00 0.04 0.08 0.12 0.16 0.20 0.24 Fe3+/Fe2+ 2.2 x 10-5 (gold)* 2 x 10-4 (mercury)* 3 x 10-6 (carbon)* 4 x 10-3 (mercury)* –1/2 (s1/2 rad–1/2) Cr3+/Cr2+ VO2+/VO2+ Koutecký-Levich Plot: Extrapolate to infinite rotation rate Gives the kinetically-limited current, iK V3+/V2+ AQDS: Rotating Disk Electrode Response exchange current density ik0 rate const k0 = ik0/(FAC) = 7.2 × 10−3 cm/s -60 -50 -40 -30 -20 -10 F = Faraday’s constant A = surface area C = concentration 1 5.8 X 10-4 (carbon)* iK 38 *Weber, A. Z.; Mench, M. M.; Meyers, J. P.; Ross, P. N.; Gostick, J. T.; Liu, Q. J. Appl. Electrochem. 2011, 41, 1137 18 23 33 363PDF Image | Organic-Based Aqueous Flow Batteries for Massive Energy
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