Organic-Based Aqueous Flow Batteries for Massive Energy

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Organic-Based Aqueous Flow Batteries for Massive Energy ( organic-based-aqueous-flow-batteries-massive-energy )

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Cell Potential (V) Discharge Capacity Retention (%) Cell Potential (V) Discharge Capacity Retention (%) • • • • Nafion 115 (125 um); 30 oC Toray carbon electrodes 2 cm2, 6 layers, no catalyst Negolyte: 1 M AQDS in 1 M H2SO4 Impose ±0.25 A/cm2 square wave, switched at 0, +1.5 V Cycle Number Cycle Number 1.8 1.6 1.4 1.2 1.0 0.8 0.6 0.4 0.2 0.0 99.986% average 100 98 96 94 1.2 100 98 96 94 92 90 88 86 84 82 80 0 20 40 60 80 100 1.8 1.6 1.4 49 50 51 52 53 0 20 40 60 80 100 120 140 160 180 200 84 82 80 0.4 0.2 0.0 Time (hrs) 100 102 104 106 108 Cycling to ~102 92 1.0 90 0.8 88 86 0.6 Capacity Retention = (Coulombs of discharge) / (immediately preceding coulombs of discharge) Posolyte: 3 M HBr + 0.5 M Br2 in H2O B. Huskinson, M.P. Marshak, M.R. Gerhardt and M.J. Aziz, “Cycling of a quinone-bromide flow battery for large-scale electrochemical energy storage”, ECS Trans. 61, 27 (2014) Time (hrs) 75

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