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Chapter 4. Molecular Electrochemistry of Quinones OH O OH O OH OH O O NaOS O O SONa O OH HO HO O HO OH O OOH OOHOH HQ HO DHBQ O O DHAQ DHTA DHPA* O OOP OH HO HO OH OOP OH OO PSAQ* OO O PPAQ* O OHO OH OO OH CN NC NC ferri/ferrocyanide 3–/4– HO OO DBEAQ CN CN O Fe CN Figure 4.1: Structural formulas and abbreviations of the redox-active compounds investigated in this work, shown in the acquired redox state. Structures marked with an asterisk (∗) were developed and synthesised in-house; the remaining struc- tures were bought commercially. HQ = hydroquinone, DHBQ = 2,5-dihydroxy-1,4- benzoquinone, DHTA = 2,5-dihydroxyterephthalic acid, DHPA = dihydroxypyromellitic acid, DHAQ = 2,6-dihydroxyanthraquinone, PPAQ = 1,4-bis(oxypropylphosphonic acid)- 9,10-anthraquinone, PSAQ = 2,6-bis(oxypropylsulfonate)-9,10-anthraquinone, DBEAQ = 4,4’-((9,10-anthraquinone-2,6-diyl)dioxy)dibutyrate. 46PDF Image | Organic Redox Flow Batteries 2023
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