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Organic Redox Flow Batteries 2023

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Organic Redox Flow Batteries 2023 ( organic-redox-flow-batteries-2023 )

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Chapter 4. Molecular Electrochemistry of Quinones Figure 4.6: RDE experiment of 5mM K4[Fe(CN)6] in 1M KCl adjusted to pH 12 with KOH recorded on a GC WE. (a) Linear sweep voltammograms recorded at 5 mV s−1 in the anodic direction at rotation rates from 100–2500 rpm. The areas shaded in blue and red show where the Levich and Koutecký-Levich currents were determined. (b) Levich plot. (c) Koutecký–Levich plot. (d) Tafel plot. The dashed lines in subplots (b)–(d) are extensions of the linear regression lines to x = 0. Figure 4.7: Side-by-side view of the Tafel plots presented in Figures 4.5 (d) and 4.6 (d). 52

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