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Appendix E Impedance Fitting Table E.1: Fixed model parameters used for modelling impedance spectra of symmetric ferri-/ferrocyanide, DHAQ, and DBEAQ cells. The electrode-specific values are valid for a single electrode (stack of 2×Sigracet 39AA papers). a According to Equation 3.51 and using d = 7 × 10−4 cm and ε = 0.80. Parameter A At b cOx cRed DOx DRed ρe (through-plane) T Species [Fe(CN)6]3– DHAQ DBEAQ [Fe(CN)6]3– DHAQ DBEAQ [Fe(CN)6]3– DHAQ DBEAQ [Fe(CN)6]3– DHAQ DBEAQ Value 5 320 0.035 1.00 × 10−4 5.00 × 10−5 5.00 × 10−5 1.00 × 10−4 5.00 × 10−5 5.00 × 10−5 6.91 × 10−6 4.8 × 10−6 2.58 × 10−6 6.02 × 10−6 4.8 × 10−6 2.58 × 10−6 0.143 304.15–308.15 Units cm2 cm2 cm mol cm−3 mol cm−3 mol cm−3 mol cm−3 mol cm−3 mol cm−3 cm2 s−1 cm2 s−1 cm2 s−1 cm2 s−1 cm2 s−1 cm2 s−1 Ωcm K Reference As prepared Calculateda Direct measurement As prepared As prepared As prepared As prepared As prepared As prepared This work [29] This work This work [29] This work Supplierspecification As prepared 149PDF Image | Organic Redox Flow Batteries 2023
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