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evaluate the behavior of this molecule within an H-cell, as an ORFB model. This work enabled the realization of the best performing high voltage non-aqueous all-organic symmetrical flow battery model to date. In single-electronic operating mode, the cell can reach more than 700 charge-discharge cycles with near-perfect Q retention and CE for a 2.12V OCV. Meanwhile, two- electron charge-discharge experiments showed the robustness and high reliability of this electrolyte beyond 15 h of continuous electrochemical stress, showing excellent CE and 100% capacity retention over 80 cycles. This [4]helicenium core is a promising new class of electrolyte for the development of high-performance symmetrical ORFBs. AUTHOR INFORMATION Corresponding Author: Thomas L. Gianetti - ORCID 0000-0002-3892-3893- University of Arizona, Department of Chemistry and Biochemistry, Tucson, Arizona, United States; tgianetti@arizona.edu; https://www.gianettigroup.com; @gianettigroup Notes The authors declare no competing financial interest. ACKNOWLEDGEMENT We are grateful for the financial support from the University of Arizona. We thank Profs. Pyun and Lichtenberger from the University of Arizona for helpful discussions. Dr. JM is grateful to Dr. Vincent Caldeira from Grenoble INP-LEPMI/Easyl for helpful discussions. REFERENCES (1) Dresselhaus, M. S.; Thomas, I. L. Alternative Energy Technologies. Nature 2001, 414 (6861), 332–337. 11PDF Image | Organic Redox Flow Battery Helical Carbeniun Ion
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