Redox Flow Batteries Concepts Chemistries

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Redox Flow Batteries Concepts Chemistries ( redox-flow-batteries-concepts-chemistries )

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TEMPO/TEMPO+ 0.30 V vs. Ag Non-aqueous - 0.1 M (1 M NaClO4 /acetonitrile) N-methylphthalimide/ N-methylphthalimide- -1.30 V vs. Ag Non-aqueous 0.1 M (1 M NaClO4 /acetonitrile) TEMPTMA/TEMPTMA+ 0.79 vs. AgCl/Ag Aqueous 4.2 x 10-3 2 M (in NaCl) -0.63 V vs. AgCl/Ag 3.3 x 10-3 Table 3 Overview of redox reactions of importance for RFBs. If approximate realised energy density is given then the energy content is calculated from the given publication. Chemistries not demonstrated in flow batteries were usually tested in a stationary cell configuration. Page 42 of 63 - Methyl Viol2+/Methyl Viol Polythiophene/Polythio phene+ +0.5 V vs. Ag/Ag+ Non-aqueous Aqueous - Suspension of polythiophene (0.1 eq. L-1 of thiophene repeating units) (1 M TEABF4 /propylene carbonate) Polythiophene/Polythio phene- -2.0 V vs. Ag/Ag+ Non-aqueous - TEMPO/TEMPO+ +0.7 V vs. Ag/AgCl (4.5 ± 0.1) x 10-4 polymer solutions (2 M NaCl) Viol2+/Viol -0.4 V vs. Ag/AgCl (9 ± 2) x 10-5 Poly(BODIPY)/Poly(BOD IPY)+ 0.69 V vs. AgNO3/Ag Non-aqueous - polymer solution (0.5 M Bu4NClO4/propylene carbonate) Poly(BODIPY)/Poly(BOD IPY)- -1.51 V vs. AgNO3/Ag Non-aqueous -

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