Redox Flow Batteries Fundamentals and Applications

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Redox Flow Batteries Fundamentals and Applications ( redox-flow-batteries-fundamentals-and-applications )

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DOI: 10.5772/intechopen.68752 Redox Flow Batteries: Fundamentals and Applications Chapter 5 Provisional chapter Redox Flow Batteries: Fundamentals and Applications Ruiyong Chen, Sangwon Kim and Zhenjun Chang Ruiyong Chen, Sangwon Kim and Zhenjun Chang Additional information is available at the end of the chapter Additional information is available at the end of the chapter http://dx.doi.org/10.5772/intechopen.68752 Abstract A redox flow battery is an electrochemical energy storage device that converts chemical energy into electrical energy through reversible oxidation and reduction of working fluids. The concept was initially conceived in 1970s. Clean and sustainable energy supplied from renewable sources in future requires efficient, reliable and cost-effective energy storage systems. Due to the flexibility in system design and competence in scaling cost, redox flow batteries are promising in stationary storage of energy from intermittent sources such as solar and wind. This chapter covers basic principles of electrochemistry in redox flow batteries and provides an overview of status and future challenges. Recent progress in redox couples, membranes and electrode materials will be discussed. New demonstration and commercial development will be addressed. Keywords: electrochemical energy storage, redox couples, electrolytes, electrodes, membranes 1. Introduction Global economic growth with the increasing release of carbon dioxide disrupts our ecosphere and causes significant impacts on climate change. An environmentally friendly route to gener- ate electricity from renewable sources such as wind and solar is desirable. To promote the utilization of renewable and sustainable energy and to enhance the stability of grid networks, energy storage systems are needed to store surplus electricity. The stored energy can be then delivered to end customers or to power grids upon need. It is becoming clear that the electro- chemical energy storage using rechargeable batteries based on redox chemistry can provide a central solution to tackle such an issue. Through storing energy in recirculating liquid electro- lytes, redox flow batteries have merits of decoupled energy density (tank size, electrolyte concentration, cell voltage and number dependent) and power generation capability (electrode size and reaction kinetics dependent). In terms of cost, system flexibility, quick response and © 2017 The Author(s). Licensee InTech. This chapter is distributed under the terms of the Creative Commons Attribution License (http://creativecommons.org/licenses/by/3.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. © The Author(s). Licensee InTech. This chapter is distributed under the terms of the Creative Attribution License (http://creativecommons.org/licenses/by/3.0), which permits unrestricted use, distribution, and eproduction in any medium, provided the original work is properly cited. Commons

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