Redox Flow Batteries Vanadium to Earth Quinones

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Redox Flow Batteries Vanadium to Earth Quinones ( redox-flow-batteries-vanadium-earth-quinones )

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4.1.3 Conclusions A reference electrode is proposed based on silver/silver sulfate inserted into filter press cells of VRFB. This reference electrode provides valuable information for “in- operando” conditions. For ammoxidized graphite felts, the hydrogen evolution at the negative electrode during the charge decreases the coulombic efficiency whereas the slower kinetics of the positive electrode contributes more to the decrease in voltage efficiency. The use of this reference electrode also opens new perspectives for the experimental routes allowing a fast, reliable and feasible way for proceeding the study, analysis and control for VRFBs. 68

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