Redox Flow Batteries Vanadium to Earth Quinones

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Redox Flow Batteries Vanadium to Earth Quinones ( redox-flow-batteries-vanadium-earth-quinones )

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1,8 1,6 1,4 1,2 1,0 150 mA/cm2 104mV E/V 56mV CF@TiO2 N500 CF@TiO2 N900 0 2 4 6 8 10 Specific Capacity / AhL-1 Figure 6.32 – Comparative between voltage profiles for CF@TiO2 N500 and CF@TiO2 N900 for current density applied of 150 mA cm-2. Subsequently, Figure 6.33a and b presents the Coulombic, Voltage and Energy efficiency for the electrodes CF, CF@TiO2 N500 and CF@TiO2 N900 respectively, as we cycle with current densities from 25 to 150 mA cm-2. The sample annealed at 900oC shows smaller losses as the current density is increased, and therefore a higher efficiency. A maximum energy efficiency of 86.5% is seen at the lowest current density (25 mA cm-2), dropping to 71% at 150 mA cm-2. These values are lower compared to the state of the art in the literature226 as a consequence of different single cell set-up design and conditions. Nevertheless, for the same experimental conditions it is clear that the coating of nitride TiO2 on the surface of the graphite felts has a drastic improvement on performance of the battery compared to CF. Similarly, the decrease in energy efficiency for CF@TiO2 N500 is markedly less than for the CF, where the efficiency decays abruptly when the current density applied increases. Especially up to 100 mA cm-2, where the value collapses due to large overpotential, as seen in Figure 6.34d. 124

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