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8 4 0 -4 -8 1.00 0.75 0.50 0.25 0.00 -0.25 -0.50 -0.75 -1.00 -0.4 20 mV/s CF-HT CF-rGO/Q CF-rGO/ROH 0.0 0.4 0.8 1.2 i / A/g i / A/g 0.0 0.1 0.2 1 mV/s CF-HT CF-rGO/Q CF-rGO/ROH 0.3 0.4 E vs. NHE / V E vs. NHE / V Figure 7.27. – Top. Cyclic voltammetry done for the electrodes CF-HT, CF-rGO/ROH and CF-rGO/Q as working electrodes of a 3 electrodes system with CF as counter electrode and Hg/Hg2SO4 as reference in a 0.05M Anthraquinone-2,7-disulfonic acid disodium salt 3 M MeSO3H solution run at a scan speed of 20 mV/s. Bottom. Cyclic voltammetry done for the electrodes CF-HT, CF-rGO/ROH and CF-rGO/Q as working electrodes of a 3 electrodes system with GF as counter electrode and Hg/Hg2SO4 as reference in a 0.05M Anthraquinone- 2,7-disulfonic acid disodium salt 3 M MeSO3H solution run at a scan speed of 1 mV/s. Table 7.7.- Electrochemical values obtained from the cyclic voltammetry showed in Figure 7.27 Left for the initial cycle. Eox /V 0.448 0.378 0.476 Electrode CF-HT CF-rGO/Q CF-rGO/ROH Ered /V -0.0797 -0.0254 -0.116 ΔE / V 0.528 0.403 0.592 Iox / mAg-1 7046.3 7064.4 5983.2 Ired / mAg-1 -6727.6 -6727.6 -5224.0 Ired/Iox 0.955 0.952 0.873 182PDF Image | Redox Flow Batteries Vanadium to Earth Quinones
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