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Figure 9.6 – Rotating disk electrode. 9.3.1.1 Solution of the Convective-Diffusion Equation The current is the flux at the electrode surface, that is, Where, under the chosen current conditions, i=il,c. From (9.52) and We obtain the Levich equation: (9.52) (9.53) (9.54) This equation applies to the totally mass-transfer-limited condition at the RDE and predicts that il,c is proportional to CO* and ω1/2. One can define the Levich constant as il,c/ω1/2CO*, which is the RDE analog of the diffusion current constant or current function in voltammetry or the transition time constant in chronopotentiometry. 232PDF Image | Redox Flow Batteries Vanadium to Earth Quinones
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