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Figure 9.8 – Koutecký-Levick plots at potential E1, where the rate of electron transfer is sufficiently slow to act as a limiting factor, and at E2, where electrons transfer is rapid, for example, in the limiting-current region. The slope of both lines is (0.62nFACO*DO2/3ν-1/6)-1. 9.3.2 Electrolyte flow Within the electrode, the flux of the various species can be described using the Nernst-Planck equation assuming that dilute-solution theory holds309. (9.63) The first term in the expression is a migration term, representing the motion of charged species that results from a potential gradient. The migration flux is related to the potential gradient (- φ2) by a charge number, zi, concentration, ci, and mobility, ui. The second term relates the diffusive flux to the concentration gradient. The final term is a convective term and represents the motion of the species as the bulk motion of the solvent carries it along. For non-charged 235PDF Image | Redox Flow Batteries Vanadium to Earth Quinones
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