Tubular Vanadium Air Redox‐flow battery

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Tubular Vanadium Air Redox‐flow battery ( tubular-vanadium-air-redox‐flow-battery )

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Study of redox flow battery systems for residential applications of VisBlue 6 battery during standard and remixing operation, instead of 3 mL, to ensure that at least three accurate essays were obtained. V5+ ions concentration of sample V6T2DisCy1091116 was determined with molar balance, assuming the total mol number (mol number of vanadium ions on negative tank and mol number of vanadium ions on positive tank) at the end of charging step at cycle 1 of VisBlue 6 standard operation equal to the total mol number of vanadium ions at the end of discharging step at cycle 1 of VisBlue 6 standard operation, also due to lack of sample volume For detailed information about the obtained results, such as used volume of titrant until each equivalence point, standard deviation and variation coefficients, are found in Appendix D. 4.4 Validation To verify if KMnO4 is, besides cheap, a feasible method to titrate vanadium electrolyte, a standardized 0.10 M Cerium (IV) sulphate (Sigma-Aldrich), Ce(IV), in 2 M sulfuric acid solution [72] was used to validate KMnO4. The procedure described on Chapter 4.3 was also used for the validation. Two 3.5+ electrolyte samples from GfE (GfE 172702) and BNM (BNM 1503814) (electrolyte containing 50 % V3+ and 50 % V4+), charged electrolyte from VisBlue 6 negative (V6T1ChaCy34141116) and positive (V6T2ChaCy34141116) tanks and discharged electrolyte from VisBlue 6 positive (V6T2DisCy34141116) tank from cycle 34 at standard operation were used to compare results. Chapter 4: Methods and materials 25

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