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1 solid-RFB, where chemical energy is stored in an active material on the electrode plate; 2 and hybrid-RFB, with solid and gaseous species involved in the redox couples. Among 3 the liquid-RFB, it is worth to mention the iron-chromium[19, 20], all vanadium (VRFB) 4 [21, 22] and other vanadium-based systems [23-26], bromine-polysulphide [27] and all 5 uranium [28] and neptunium [29, 30] and non-aqueous electrolytes system [31-33]. The 6 solid-RFB includes soluble lead-acid [34, 35], zinc-nickel [36, 37] and zinc-manganese 7 dioxide [38]. Finally, the hybrid-RFB includes several zinc-based systems [10, 39-42], 8 vanadium-air [43], organic redox couples [44, 45] and lithium flow batteries [46, 47]. 9 In this work, a redox flow battery using the different oxidation states of the 10 vanadium as energy storage system is evaluated (Vanadium Redox Flow Battery, VRFB). 11 This type of batteries was proposed in the mid-1980s by the Professor Skyllas-Kazacos’s 12 group, belonging to the University of New South Wales (UNSW) [48-52], obtaining 13 patent in 1986 (AU Patent 575247-1986). Since then, the development of this technology, 14 even for the industrial application, has been world-wide spread [53-55]. Reactions 15 involved on the performance of the all vanadium redox flow batteries include equation 1 16 on the positive electrode and equation 2 on the negative electrode, being the overall 17 reaction shown in equation 3. E0=1.00 V (1) E0=-0.26 V (2) VO2 V3 H O 21 Taking into account these considerations, the main objective of this work is to 22 evaluate the application of vanadium redox flow battery system (VRFB) as storage of the 4 18 VO 2H e Discharge VO2 H O 19 V2 20 VO V2 2H 2 2 V3 e Discharge Charge Discharge Charge 2 2 E0=1.26 V (3) ChargePDF Image | Vanadium Redox Flow Batteries for wind turbines
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