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ARTICLE NATURE COMMUNICATIONS | https://doi.org/10.1038/s41467-021-21488-7 mounted onto a SEM sample stage (Ted Pella) and transferred into the FEI Scios DualBeam FIB/SEM using the air-sensitive holder to avoid any ambient air exposure. Cross sections were milled using the FIB and SEM images were taken of the samples. Data availability The datasets generated and/or analyzed during the current study are available from the corresponding author on reasonable request. The X-ray crystallographic coordinates for the structures reported in this study, Na3YCl6 and Na2ZrCl6, have been deposited at the Cambridge Crystallographic Data Centre (CCDC), under deposition numbers 2057626-2057627. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via www.ccdc. cam.ac.uk/data_request/cif. 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