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Materials 2022, 15, x FOR PEER REVIEW 9 of 15 Materials 2022, 15, 6231 9 of 15 Figure 4. (a,b) Ex situ XRD patterns obtained at selected cutoff potentials in initial sodiation/deso- Figure 4. (a,b) Ex situ XRD patterns obtained at selected cutoff potentials in initial sodia- diation process; (c) schematic of electrochemical reaction mechanism of Ga2Te3–TiO2–C(10%) elec- tion/desodiation process; (c) schematic of electrochemical reaction mechanism of Ga2Te3–TiO2– trode during cycling. C(10%) electrode during cycling. For the first, fifth, and 20th cycles, the EIS profiles of the Ga2Te3–TiO2–C(10%), Ga2Te3–TiO2–C(20%), and Ga2Te3–TiO2–C(30%) electrodes were obtained (Figure 5). The simplified equivalent circuit shown in Figure 5d includes the electrolyte resistance (Rb), charge-transfer resistance (Rct), SEI layer resistance (RSEI), interfacial double-layer capaci- tance (Cdl), Warburg impedance (Zw), and constant phase element (CPE). The Rct at the elec-PDF Image | Ga2Te3-Based Anodes for Sodium-Ion Batteries
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