Polymer Electrode Materials for Sodium-ion Batteries

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Polymer Electrode Materials for Sodium-ion Batteries ( polymer-electrode-materials-sodium-ion-batteries )

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Materials 2018, 11, 2567 Materials 2018, 11, x FOR PEER REVIEW 7 of 18 7 of 20 (a) (b) (c) (d) (e) (f) ∙ ∙ ∙ ∙ ∙ ∙ Figure 4. (a) Fourier transform infrared spectra of 2,5-dichloro-3,6-dihydroxy-p-quinone (CLA) and Figsoudreiu4m. (sa)ltFofuprioelry(t2ra,5n-sdfiohrymdrionxfrya-rpe-dbesnpzeocqturainofn2y,l5s‐duilcfihdleo)ro(N‐3a,6‐PdDihSy)d; (rbo)xyp‐hpo‐qtouginraopnhe o(Cf tLhAe)CaLnAd sopdoiuwmdesraaltndofthpeoNlya(2,P5D‐dSiheyledcrtoroxdy‐epi‐nbethnezoeqleucitnronlytle;s(ucl)fiCdVe)cu(Nrvae2PsDofSt)h;e(bN)aphPoDtSogerlaecpthroodfetahteaCscLaAn 22 −1 porwatdeeorfa0n.d1mthVeN·sa2P;D(dS)edliescthroadrgeeinanthdecehlaercgtreoplyrtoefi;l(ec)sCofVthcuerNveasPofDtShelNecat2rPoDdSeealteactcruordrenatadescnasnityraotef −1 −11 of10.01mAV·ꞏgs ;;(de)rdaitsechpaerfgoermanadnccehanrdge(fp)rcoyfciliensgopfetrhfoermNan2PcDeoSfeCleLcAtroanddeNataaPcDuSrraesnctadnednidsiattyeoanfo1d0e0 2 mAmꞏagte;ri(ael)sfroartesopdeirufomrm-ioancbeatatnedrie(sf.)Acydcalpintgedpferrofmorm[5a0n],cweiotfhCpLerAmaisnsdionNfar2oPmDS©a1s9c9a6nRdoidyatleSoancioedtye maotfeCrihaelsmfiosrtrsyo. dium‐ion batteries. Adapted from [50], with permission from © 1996 Royal Society of Chemistry. 2.2. Schiff Base Polymer Electrode Materials 2.2.1. Synthesis and Structural Diversity 2.2.1. SSycnhthifefsbiassaenpdoSlytrmucetrusrcalnDbievesrysnityhesized by a simple polycondensation reaction of diamines and dialdehydes or diketones [51]. Schiff base polymers contain a system of conjugated –C=C– and –C=N– Schiff base polymers can be synthesized by a simple polycondensation reaction of diamines and 2.2. Schiff Base Polymer Electrode Materials bonds. The structure of diamine and dialdehyde or diketone precursors determines the diversity of dialdehydes or diketones [51]. Schiff base polymers contain a system of conjugated –C=C– and –C=N– the Schiff base polymers (Figure 5). bonds. The structure of diamine and dialdehyde or diketone precursors determines the diversity of the Schiff base polymers (Figure 5). 2 2

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