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Chem Soc Rev Review Article Fig. 4 (a) Charge and discharge curves of P2-Na2/3[Fe1/2Mn1/2]O2 and (b) SXRD patterns of P2-Na2/3[Fe1/2Mn1/2]O2 samples charged to 3.8 and 4.2 V in which the P2 phase was transformed into OP4 one. (Reproduced by permission from ref. 46, Nature Publishing Group, Copyright 2012.) (c) Operando in situ XRD patterns of the P2-Nax[Fe1/2Mn1/2]O2 electrode. The red XRD patterns correspond to the limits of the different structural domains: P02 phase for x = 0.85–0.97 in Nax[Fe1/2Mn1/2]O2 and Z-phase for x = 0.25–0.35 in Nax[Fe1/2Mn1/2]O2. (Reproduced with permission from ref. 55, Copyright 2011 The Royal Society of Chemistry.) (d) First cycle for 1.5–4.0 V (dashed lines) and 1.5–4.25 (solid lines) for selected cells. (Reproduced with permission from ref. 57, Copyright 2013 The Electrochemical Society.) (e) In situ synchrotron XRD patterns of the P2-Na0.7[Fe0.4Mn0.4Co0.2]O2. (Reproduced from ref. 58 with permission, Copyright 2015 Wiley-VCH Verlag GmbH & Co. KGaA.) (f) First charge and discharge curves of the Nax[Fe1/2Mn1/2]O2/NaN3 composite electrode. (Reprinted from ref. 60, Copyright 2013, with permission from Elsevier). View Article Online Thisjournalis©TheRoyalSocietyofChemistry2017 Chem.Soc.Rev.,2017,46,3529--3614 | 3535 Open Access Article. Published on 28 March 2017. Downloaded on 7/1/2019 3:41:21 AM. This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.PDF Image | Sodium-ion batteries present and future
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