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Review Article Chem Soc Rev Fig.8 (a) Crystal structure of monoclinic O03-Na0.93MnO2 projected in the a–c-plane and (b) charge and discharge curves of monoclinic O03-Na0.93MnO2. (Reproduced with permission from ref. 90, Copyright 2011 The Electrochemical Society.) (c) Schematic illustration of orthorhombic P02-Na0.7MnO2. (Reprinted from ref. 95, Copyright 2010, with permission from Elsevier.) (d) Charge and discharge curves of P2-Na2/3MnO2. (Reproduced with permission from ref. 99, Copyright 2014 American Chemical Society.) (e) Charge and discharge curves of P2-Na2/3[Ni1/3Mn2/3]O2 (Reproduced with permission from ref. 101, Copyright 2001 The Electrochemical Society), in which the inset represents the diffusion paths of P2 (left) and O2 (right) that favors diffusion in the P2 phase (Reproduced with permission from ref. 103, Copyright 2013 The Royal Society of Chemistry) and (f) in situ powder X-ray diffraction of Na2/3[Ni1/3Mn2/3]O2 showing the reversible evolution of P2–O2 phase transition. (Reproduced with permission from ref. 101, Copyright 2001 The Electrochemical Society.) View Article Online which is associated with the P2 phase reaction, resulted in excellent cycling behavior retaining 96% of the initial capacity (B80 mA h g1). They further extended their work to inhibit O2 phase formation in a deeply desodiated state to retain the capacity for a long-term. Surprisingly, Li substitution in the transition metal layer, Na0.80[Li0.12Ni0.22Mn0.66]O2, inhibited 3542 | Chem. Soc. Rev., 2017, 46, 3529--3614 This journal is © The Royal Society of Chemistry 2017 Open Access Article. Published on 28 March 2017. Downloaded on 7/1/2019 3:41:21 AM. This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.PDF Image | Sodium-ion batteries present and future
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