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Chem Soc Rev Review Article Fig. 15 (a) The crystal structure of a-Na3Al2(PO4)2F3 along the a-axis. (Reprinted from ref. 182, Copyright 1999, with permission from Elsevier.) (b) Electrochemical performance data for a typical hard carbon//NaVPO4F cell. (Reproduced with permission from ref. 181, Copyright 2003 The Electrochemical Society.) (c) The crystal structure of Na1.5VOPO4F0.5 in the (ac) plane and (d) the P.I.T.T. curve of the composite Na1.5VOPO4F0.5/C recorded at a 1Na/100 h rate. (Reprinted from ref. 186, Copyright 2006, with permission from Elsevier.) (e) The crystal structure of Na1.5VPO4.8F0.7 and two different local environments for V4+ and V3+ ions (i.e., VO5F and VO4F2 octahedra, respectively): Na (yellow), V cyan), P (purple), O (red), and F (green) atoms and Na layers denoted as dashed boxes and (f) charge–discharge profile at a C/10 rate for the Na1.5VPO4.8F0.7 cathode (voltage window: 2.0–4.5 V vs. Na+/Na) appeared with the average voltage (3.8 V vs. Na+/Na) as a horizontal dotted line. (Reproduced with permission from ref. 187, Copyright 2013 American Chemical Society.) (g) Synchrotron radiation diffraction data in the P42/mnm space group (top) and in the low-symmetry orthorhombic group Amam (bottom). (Reproduced with permission from ref. 191, Copyright 2014 American Chemical Society.) and (h) first charge and discharge curves for Na3V2(PO4)2F3 a rate of 0.2 mA cm2. (Reprinted from ref. 190, Copyright 2013, with permission from Elsevier.) View Article Online Thisjournalis©TheRoyalSocietyofChemistry2017 Chem.Soc.Rev.,2017,46,3529--3614 | 3553 Open Access Article. Published on 28 March 2017. Downloaded on 7/1/2019 3:41:21 AM. This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.PDF Image | Sodium-ion batteries present and future
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