Sodium-ion batteries present and future

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Review Article Chem Soc Rev Fig. 21 (a) Graphite current–potential curve in the graphite/PEO-NaCF3SO3/Na cell at 82 1C. (Reprinted from ref. 254, Copyright 1988, with permission from Elsevier.) (b) Li+ and Na+ insertion mechanisms in graphene and graphite. (Reproduced by permission from ref. 255, Nature Publishing Group, Copyright 2015.) (c) In operando synchrotron X-ray diffraction analysis of the structural evolution of the ternary Na–ether–graphite system. (Reproduced with permission from ref. 261, Copyright 2015 The Royal Society of Chemistry.) (d) Different Na storage mechanisms in natural graphite between in NaPF6 in EC/DEC (top) and NaPF6 in DEGDME (bottom). (Reproduced from ref. 262 with permission, Copyright 2015 Wiley-VCH Verlag GmbH & Co. KGaA.) (e) In situ TEM investigation of the sodium storage mechanism in the EG-1h sample. (f) Electrochemical performances of PG, GO, EG-1h and EG-5h in organic 1.0 M NaClO4 in a polycarbonate solvent liquid electrolyte. (Reproduced by permission from ref. 263, Nature Publishing Group, Copyright 2014.) View Article Online (SAXS) in the voltage range of 0.2 V to 0 V (in the plateau region) upon reduction. From these results, they suggested that the enlarged interlayer spacing (d-spacing = 3.8 Å) or the smaller crystallite size of the parallel graphene within hard-carbon in 3562 | Chem. Soc. Rev., 2017, 46, 3529--3614 This journal is © The Royal Society of Chemistry 2017 Open Access Article. Published on 28 March 2017. Downloaded on 7/1/2019 3:41:21 AM. This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.

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