Sodium-ion batteries present and future

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Review Article Chem Soc Rev Table 1 Summary of cathode materials for sodium-ion batteries Cathode materials for sodium-ion batteries View Article Online Structure Two-dimensional layer transition metal oxide Na1􏰣xFeO2 Compositions NaFeO2 Na[Fe0.5Mn0.5]O2 Na[Fe0.5Co0.5]O2 Na[Fe0.3Ni0.7]O2 Na[Ni1/3Fe1/3Mn1/3]O2 Na[Ni0.25Fe0.5Co0.25]O2 Na[Ni0.25Fe0.5Mn0.25]O2 Na[Li0.05(Ni0.25Fe0.5Mn0.25)0.95]O2 Na2/3[Fe0.5Mn0.5]O2 Na0.62[Fe0.5Mn0.5]O2 Na0.7[Fe0.5Co0.5]O2 NaCoO2 Na0.55CoO2 Na2/3[Co2/3Mn1/3]O2 Na5/8Ca1/24CoO2 NaNiO2 Na[Ni0.5Mn0.5]O2 NaFe0.2Ni0.4Mn0.4O2 Na[Ni0.5Ti0.5]O2 NaMnO2 Na0.7MnO2 Na2/3[Ni1/3Mn2/3]O2 Na2/3[Ni1/3􏰣xMgxMn2/3]O2 Na2/3[Ni1/3􏰣xAlxMn2/3]O2 Na2/3[Ni1/3􏰣xFexMn2/3]O2 Na0.7[Mn0.65Ni0.15Fe0.2]O2 Na2/3[Ni1/3􏰣xCoxMn2/3]O2 Na2/3[Ni1/3􏰣xZnxMn2/3]O2 Na0.7[Mn0.6Ni0.3Co0.1]O2 Na2/3[Ni1/3Mn1/6Ti1/6]O2 Na2/3[Mg0.28Mn0.72]O2 Na5/6[Li1/4Mn3/4]O2 Na0.85[Li0.17Ni0.21Mn0.64]O2 NaTiO2 NaCrO2 NaVO2 Na0.7VO2 Na2RuO3 Redox Voltages couples (V) Fe3+/4+ 1.3–4 Fe3+/4+ 1.5–4.2 Mn3+/4+ Fe3+/4+ 2.5–4.0 Co3+/4+ Fe3+/4+ 2.0–3.6 Ni3+/4+ Ni2+/4+ 2–4 Fe3+/4+ Co4+ Ni2+/4+ 2.1–3.9 Fe3+/4+ Co4+ Ni2+/4+ 2.1–3.9 Fe3+/4+ Ni2+/4+ 1.7–4.4 Fe3+/4+ Fe3+/4+ 1.5–4.3 Mn3+/4+ Fe3+/4+ 1.5–4.3 Mn3+/4+ Fe3+/4+ 2.5–4.0 Co3+/4+ Co3+/4+ 2.0–4.0 Co3+/4+ 2.7–3.5 Co2+/3+ 1.5–4.3 Mn3+/4+ Co3+/4+ 2.0–4.0 Ni3+/4+ 2.0–4.5 Theoretical capacity (mA h g􏰣1) 241 242 240 237 239 239 240 246 260 263 256 239 263 258 255 Experimental capacity (mA h g􏰣1) 125 100–110 160 135 120 140 140 180 190 185 170 170 140 180 124 145 121 185 125 124 130 121 197 150 216 198 162 120–145 147 145 208 144 140 185 127 220 180 200 75 110 120 105 147 Ref. 49 46 47 39 50 51 52 52 54 55 47 33 62 73 and 74 79 81 81 83 83 84 84 88 90 98 97 97 101, 107 and 113 107 113 113 117 113 111 and 112 114 118 and 119 120 121 7 124 and 125 126 134 136 137 Na1􏰣x[Fe1􏰣yMny]O2 Na1􏰣xCoO2 Na1􏰣xNiO2 NaxMnO2 235 1.25–3.75 235 Ni2+/4+ 2.0–4.5 2.2–3.8 239 Na1􏰣xTiO2 Na1􏰣xCrO2 Na1􏰣xVO2 Na2RuO3 Fe3+/4+ 2.0–4.0 Ni3+/4+ Ni2+/4+ 1.5–4.7 Mn3+/4+ 2–3.8 Mn3+/4+ 2–3.8 Mn3+/4+ 1.5–4.4 Mn3+/4+ 1.5–4.4 Ni2+/4+ 2.0–4.5 Ni2+/4+ 2.0–4.5 Ni2+/4+ 2.0–4.5 Fe3+/4+ 2.0–4.5 Ni2+/4+ Fe3+/4+ 1.5–4.3 Ni2+/4+ Ni2+/4+ 2.0–4.5 Ni2+/4+ 2.2–4.3 Ni2+/4+ 1.5–4.3 Ni2+/4+ 2.5–4.5 Mn3+/4+ 1.5–4.4 Mn3+/4+ 1.5–4.4 Ni2+/4+ 1.5–4.4 Mn3+/4+ Ti3+/4+ 2.0–3.5 Cr3+/4+ 2–3.6 V4+/3+ 1.2–2.4 V4+/3+ 1.2–2.6 Ru4+/5+ 1.5–4.0 240 247 243 260 260 260 258 Around 258 Around 258 Around 258 258 Around 258 Around 258 256 319 286 267 266 260 250 253 270 137 3598 | Chem. Soc. Rev., 2017, 46, 3529--3614 This journal is © The Royal Society of Chemistry 2017 239 2.0–4.0 239 Open Access Article. Published on 28 March 2017. Downloaded on 7/1/2019 3:41:21 AM. This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.

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