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Sulfur Dioxide and Sulfolane Sodium Batteries

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Sulfur Dioxide and Sulfolane Sodium Batteries ( sulfur-dioxide-and-sulfolane-sodium-batteries )

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Batteries 2022, 8, x FOR PEER REVIEW 3 of 13 Batteries 2022, 8, 127 3 of 13 by many authors [5,6]. In contrast, when a certain amount of additive is present in the electrolyte, the trend observed during cycling changes. In fact, the addition of SO2 mole fractions of 0.02 or 0.05 consistently leads to a stabilization of the sodium plating/stripping fractions of 0.02 or 0.05 consistently leads to a stabilization of the sodium plating/stripping process, the voltammograms experiencing less changes upon repeated cycling. Further process, the voltammograms experiencing less changes upon repeated cycling. Further information about the evolution of the voltammetric response upon 10 cycles for each information about the evolution of the voltammetric response upon 10 cycles for each elec- electrolyte and SO2 concentration is provided in the Supplementary Materials (Figures S1– trolyte and SO2 concentration is provided in the Supplementary Materials (Figures S1–S3). S3). FigFuirgeur1e. 1C. Cyycclilcicvollttammograms iinththeepprerseesnecneceanadntdhethaebsaebnscenocfeSoOf2 SfoOr2NfaorelNecatroedleecstriondeisffeinrent organic electrolytes: (a) 2 M NaTf/DOL:DME, (b) 1.6 M NaTf/DOL:DME; (c,d) 2 M NaSCN/DOL:DME different organic electrolytes: (a) 2 M NaTf/DOL:DME, (b) 1.6 M NaTf/DOL:DME; (c,d) 2 M and (e,f) 1 M NaClO4/PC at 20 mV s−1. −1 NaSCN/DOL:DME and (e,f) 1 M NaClO4/PC at 20 mV s . On the other hand, colored curves in Figure 1b,d,f correspond to the tenth cycle for each SO2 concentration and for each electrolyte. By comparing them with the CVs in the absence of additive, a decrease of the currents is generally observed. The ohmic behavior of the voltammograms allows us to describe them in terms of resistances. In a comprehensive work on lithium plating, based mainly on voltammetric measurements, Genovese et al. calculated the so-called plating resistance from the slope of the current–potential curve

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