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List of Figures 1.1 Phenomenaincomplexoxides .................... 1 1.2 ApplicationsofSmNiO3 ....................... 3 1.3 BandgapmodelforREoxides.................... 5 1.4 UnitcellofRNiO3crystals...................... 6 1.5 Unit cell structure of selected Ruddlesden-Popper phases . . . . . 7 1.6 Phasediagramofrareearthnickelates . . . . . . . . . . . . . . . 9 1.7 ThecrystalstructureofNdNiO3. .................. 12 1.8 Distribution of electronic cloud in eg and t2g orbitals. . . . . . . . 13 1.9 Schematic image of main metal-insulator transition types . . . . . 15 1.10StabilityofSmNiO3.......................... 25 1.11 Predicted updated diagram for thermodynamic phase stability of selectedRNiO3compounds...................... 26 1.12 Application of the SNO film as a transistor and capacitor . . . . . 32 1.13 I-VcharacteristicsofSNOrectifyingdevice. . . . . . . . . . . . . 33 2.1 DiffractionofX-raysbyaperfectcrystal. . . . . . . . . . . . . . . 36 2.2 XRDpattenofSNOpowder...................... 39 2.3 AxesandanglesinanXRDmeasurement . . . . . . . . . . . . . 39 2.4 Schemeofgenerationoffluorescentradiation . . . . . . . . . . . . 40 2.5 Energy dependence of the mass absorption coefficient μ for several elements................................ 41 2.6 XPSsurveyspectrumofSmNiO3 .................. 45 2.7 Shake-upandshake-offsatellites. .................. 46 2.8 Multiplet structure of 2p vacancy in nickel spectra . . . . . . . . . 50 2.9 Exemplary XPS spectra of Ni2p3/2 that show a complicated com- positionofthenickelenvelope.................... 51 2.10 Force between the sample and the scanning spm tip as a function oftheirseparationdistance...................... 53 xiiiPDF Image | Investigation of metal-insulator transition in magnetron sputtered samarium nickelate thin films
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