Investigation of metal-insulator transition in magnetron sputtered samarium nickelate thin films

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Investigation of metal-insulator transition in magnetron sputtered samarium nickelate thin films ( investigation-metal-insulator-transition-magnetron-sputtered )

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2. EXPERIMENTAL METHODS of the nickel state. Those calculations were the basis for analysis of spectra for certain nickel compounds in other works, for example Grosvenor et al. (43). The results of their work is presented in figure 2.9. Further work on quantification of the chemical states in nickel compounds is done by Biesinger et al. (11). Figure 2.8: Multiplet structure of 2p vacancy in nickel spectra - Zero energy is an arbitrary point. Intensity is normalized in the same manner for all spectra. As presented in (46) In the primary work by Gupta and Sen, several spectra for multiplet struc- ture of 2p vacancies created in TM ions were calculated. The calculations took into account spin-orbit splitting (interaction). However crystal field effects were substituted by some approximation by Lo ̈wdin, and ground-state configuration was used instead of other (therefore satellites are not correctly predicted). 50

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