Methods for Chemical Analysis of Water and Wastes

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Methods for Chemical Analysis of Water and Wastes ( methods-chemical-analysis-water-and-wastes )

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OptImum ConcentratIon Range: Detection LimIt: 1 ug/l 5-100 ug/l CHROMIUM Method 218.2 (Atomic Absorption, furnace technique) PreparatIon of Standard SolutIon 1 StocksolutIOn Prepareasdescnbedunder"dIrectaspIratIonmethod" 2 Calcmm NItrate SolutIOn DIssolve 11 8 grams of calcmm mtrate, Ca(N03)2 • 4H20 (analytIcal reagent grade) m delOmzed mstl1led water and dIlute to 100 ml 1 ml = 20 mg Ca 3 Prepare ddutions of the stock chrommm solutIOn to be used as cahbratlOn standards at the tIme ofanalysIs The cahbratlOn standards should be prepared to contam 05% (v/v) HN03 To each 100 ml ofstandard and sample ahke, add 1ml of30% H20 2 and 1ml of the calcmm filtrate solutIOn Sample PreservatIOn 1 For sample handhng and preservatIOn, see part 41 of the AtomIC AbsorptIon Methods section of thIS manual Sample PreparatIon 1 Prepare as descnbed under "dIrect aspIratIOn method" Sample SolutIons for analysIs shou1dcontamO 5% v/vHN03 Instrument Parameters (General) 1 DrymgTImeandTemp 30sec-125°C 2 AshmgTImeand Temp 30sec-10oo°C 3 AtomIzmg TIme and Temp 10 sec-27oo°C 4 Purge Gas Atmosphere Argon 5 Wavelength 357 9 nm 6 Other operatmg parameters should be set as specIfied by the partIcular mstrument manufacturer AnalysIs Procedure 1 For the analysIs procedure and the calculatIOn, see "Furnace Procedure" part 9 3 of the AtomIC AbsorptIOn Methods sectIon of thIS manual Approved for NPDES and SDWA Issued 1978 2182-1 STORET NO. 01034 Dissolved 01030 Suspended 01031

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