Methods for Chemical Analysis of Water and Wastes

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Methods for Chemical Analysis of Water and Wastes ( methods-chemical-analysis-water-and-wastes )

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6 2 Color companson 7 8 1 6224 Read the sulfide concentratiOn from the calibratiOn curve CalculatiOns 7 1 VIsual comparIson WIth methylene blue solutiOn I (56), adjusted so that 005 ml (1 drop) = 1 0 mg/1 sulfide and a 7 5 ml sample mg/1 sulfide = number drops methy:lene blue solutiOn I (5 6) + 0 1 x [number of drops methylene blue solutiOn II (5 7)] 7 2 PhotometrIc see 6 2 2 4 PrecIsIon and Accuracy 8 1 The precIsIon has not been determmed The accuracy IS about ±10% BIbliography Standard Methods for he ExammatiOn ofWater and Wastewater, 14th edItiOn, p 503, Method 428C(1975) 621 VIsual 62 1 1 62 1 2 Add methylene blue solutiOn I (56) and/or II (57) (dependmg on sulfide concentratiOn and accuracy desIred) dropwise to tube B (6 14) untIl the color matches that developed m the first tube If the concentratiOn exceeds 20 mg/1, repeat 6 2 11 usmg a portiOn of the sample dl1uted to one tenth 6 2 2 Photometnc 6221 Usea 1cmcellfor0 1to20mg/1 Usea 10cmcellforupto20mg/1 6222 ZeromstrumentwIthportiOnofsamplefromtubeB(6 14) 6223 Prepare calibratiOn curve from data obtamed m methylene blue standardIzatiOn (5 8), plottmg concentraton obtamed from tItnmetnc iOdIde procedure (Method 376 1) versus absorbance A straIght hne relatiOnshIp can be assumed from 0 to 1.0 mg/1 3762-3

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