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7 9 8 CalculatiOn 8 1 RxD and standards are measured by constructmg a straight baseline over the range of the scan I and measunng the absorbance of the peak maXimum at 2930 cm- and subtractmg the baselineabsorbanceatthatpomt ForanexampleofatypiCal011spectrumandbaseline constructlOn, see Gruenfeld(3) Non-scanmng mstruments should be operated accordmg to manufacturer's mstructiOns, although cahbratiOn must be performed usmg the standards descnbed above (64) If the absorbance exceeds 08 for a sample, select a shorter pathlength or dilute as reqUired Use a cahbratiOn plot of absorbance vs mg 011 prepared from the standards to determme the mg 011 m the sample solutiOn mg/l total 011 and grease = V where R = 011 m solutiOn, determmed from cahbratiOn plot, m mllhgrams D = extract dllutlOn factor, ifused V = volume of sample, determmed by refilhng sample bottle to cahbratlOn Ime and correctmg for aCid addition ifnecessary, m hters 9 PrecisiOn and Accuracy 9 1 The two 011 and grease methods m this manual were tested by a smgle laboratory (EMSL) on sewage This method determmed the 011 and grease level m the sewage to be 17 5 mg/l When 1hter portiOns ofthe sewage were dosed With 140 mg ofa mixture of #2 fuel 011 and Wesson 011, the recovery was 99% With a standard deviatlOn of ±14 mg/l Blbbograpily 1 Standard Methods for the ExammatiOn of Water and Wastewater, 14th Edition, p 516, Method 502B, (1975) 2 Amencan Petroleum Institute, "Manual on Disposal of Refinery Wastes", Vol IV, Method 733-58 (1958) 3 Gruenfeld, M, "ExtractlOn of Dispersed 011s from Water for Quantitative AnalySiS by Infrared Spectroscopy", EnViron SCi Technol L...636 (1973) 413 2-3PDF Image | Methods for Chemical Analysis of Water and Wastes
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