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Two-Dimensional Borophene

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Two-Dimensional Borophene ( two-dimensional-borophene )

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14 Research Liquid exfoliation NMP/Ethanol Thermal oxidation etching Water (a) B+O2 B2+O3 20 0 H+ exfoliation B2+O3+3H2O 2BO33-+6H+ Liquid BO33- (b) (c) 0 AA 400 800 (d) 𝛽12 X3 5 nm B B (f) (e) Figure 13: (a) Schematic representation of borophene. (b) HRTEM image, (c) TEM image, and (d) AFM image. Reprinted with permission from Ref. [62]. Copyright 2018 John Wiley & Sons, Inc. (e) Diagrammatic drawing of liquid-phase exfoliation preparation of borophene. (f) HRTEM of borophene sheet with two phases. Reprinted with permission from Ref. [86]. Copyright 2018 Royal Society of Chemistry. 400 300 200 100 0 a-direction (b) b-direction TF TF BR (325.1 meV) BF (2.6 meV) 012345678 Diffusion coordinate TF-BR-TF TF-BF-TF (a) (c) Figure 14: (a) Energy barriers and (b, c) pathways of Li movement alongside serrate and armchair directions. Reproduced from Ref. [90]. Copyright 2016 Elsevier B.V. ↑ ↑ Relative energy (meV)

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