Triboelectricity: Macroscopic Charge Patterns Formed by Self- Arraying Ions on Polymer Surfaces

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Triboelectricity: Macroscopic Charge Patterns Formed by Self- Arraying Ions on Polymer Surfaces ( triboelectricity-macroscopic-charge-patterns-formed-by-self- )

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Langmuir Article Figure 3. Charge elimination on PTFE using different liquids. Potential map in (a) PTFE after tribocharging with PE foam and (b) following immersion in ethanol for 2 h and drying under air. (c) Effect of solvents on the electric potential of six different areas (three positive, three negative) of PTFE tribocharged with PE foam. The electric potential on PTFE was measured before tribocharging (red bars), right after tribocharging with PE foam (green), and after washing with each liquid (blue). miscibility. Partial mixing may also take place but only involving oligomer fractions and eventual contaminants. There is always material transfer among two contacting polymer surfaces,45,46 as well as under mild polymer−metal contact conditions.47 This is facilitated when the polymer surfaces are covered with weakly bound layers (WBLs)48,49 that are fairly universal and are formed by oligomers, misfit polymer chains, and impurities that are less dependent on the restrictions imposed by Flory−Huggins theory. On the other hand, material transfer among surfaces and its deposition on any surface is directed by the balance of relevant interfacial and surface tensions: interfacial areas with low interfacial tension tend to grow at the expense of the areas with higher surface tension.50,51 Mutual friction of the contacting surfaces increases the contact area and it forces one polymer to spread on top of the other under nonequilibrium conditions, even if the balance of interfacial forces mentioned in the previous paragraph is not favorable. Moreover, temperature peaks and high shear in the previously mentioned hot spots allow the formation of short- lived, highly unstable species, or triboplasma.52−54 Extensive chain breakdown takes place, due to the combination of high temperature and mechanical pull of the entangled polymer chains. Polymer chain breakdown can be heterolytic or homolytic.55 In the former case, ionic chain-ends are formed, more or less fixed to the subsurface layers by the intact chain segments. Given the stochastic characteristics of electron distribution in ruptured chain bonds, equal amounts of positive and negative ions can be formed on both contacting surfaces, but only the most stable are expected to survive for longer periods. 7411 dx.doi.org/10.1021/la301228j | Langmuir 2012, 28, 7407−7416

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