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Accumulateur Lithium Soufre

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Accumulateur Lithium Soufre ( accumulateur-lithium-soufre )

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Chapter 2: S8 electrode on Aluminum Figure 2-18. An illustrative summary of different phenomena appearing in S8 electrode, responsible for Nyquist plot shape recorded by EIS on a symmetric sulfur-based coin cell. A significant difference in the EIS response was observed for three prepared electrodes (CMCdispermat, PVdFmanual, PVdFdispermat), mostly due to the differences in the electrode elaboration process. We were interested to determine if a correlation between the EIS response and cycling performances could be established. Post mortem studies on cycled electrodes were done, and the results are presented in the following section. 2.3.4. Correlation of the EIS results with cycling performances 2.3.4.a) Cycling results In order to have the most comparative and reflective results, we took into consideration highly loaded electrodes (with sulfur loading of ~ 3.9 – 4.7 mg cm-2) cycled at faster rate (C/5).** Figure 2-19 shows the shape of the initial voltage profile, together with capacity retention. ** For thin electrodes cycled at a slow rate (C/20), no difference in the potential value was observed. 66

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