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example, would probably help to proceed the lower plateau much longer, and thus to obtain improved electrochemical response. However, such solution may induce additional parasitic reactions of electrolyte or faster reduction of LiNO3 additive. Furthermore, this observation also proves that such electrodes and cell configuration are not designed for power application. (a) (b) Chapter 3: S8 electrode on NwC Figure 3-7. Galvanostatic cycling results of ‘S-on-NwC’ electrodes at different C-rates applied for prolonged cycling: capacity retention (a) coulombic efficiency values calculated as a ratio of (n) discharge / (n) charge (b). Figure 3-8 shows corresponding voltage profiles together with overpotential values calculated from the derivative curves (dQ/dE vs. E) for each C-rate and at equilibrium (after potential relaxation). Figure 3-8. Initial voltage profile of ‘S-on-NwC’ electrodes cycled at different C-rates. The overpotential is higher for the discharge processes than for the charge ones, moreover, lower discharge plateau is affected in higher extent than the upper plateau. This could be 81PDF Image | Accumulateur Lithium Soufre
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