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Figure 1. The use of TiO2 for Li-S batteries. a) FTIR spectra (top) of α-TiO2, Li2S4, and α- TiO2/Li2S4, and Raman spectra (bottom) of α-TiO2 and α-TiO2/Li2S4. Peaks characteristic of the material are highlighted with arrows. b) Schematic diagram of the synthetic process (top), and SEM and TEM images (bottom) of as-synthesized sulfur-TiO2 yolk-shell nanostructures. Scale bars, 2 μm and 1 μm for SEM and TEM, respectively. c) Capacity retention of sulfur- TiO2 yolk-shell nanostructures and control samples cycled at 0.5 C. a) Reproduced with permission.[34] Copyright 2012, American Chemical Society. b,c) Reproduced with permission.[36] Copyright 2013, Nature Publishing Group. 28PDF Image | Advances in Polar Materials for Lithium-Sulfur Batteries
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